SYNTHESIS AND STRUCTURE OF THE SMALLEST CYCLIC CUMULENE - REACTION OF 1,3-DIYNES WITH ZIRCONOCENE COMPLEXES

被引：141

作者：

ROSENTHAL, U ^{[1
]}

OHFF, A ^{[1
]}

BAUMANN, W ^{[1
]}

KEMPE, R ^{[1
]}

TILLACK, A ^{[1
]}

BURLAKOV, VV ^{[1
]}

机构：

[1] RUSSIAN ACAD SCI,INST ORGANOELEMENT CPDS,MOSCOW,RUSSIA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 15-16期

关键词：

D O I：

10.1002/anie.199416051

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The unexpected result of the reaction of “Cp2Zr” with di‐tert‐butadiyne was the formation of 1, the smallest possible cyclic cumulene. Other disubstituted butadiynes reacted with “Cp2M” by cleavage, dimerization, or dinuclear complex formation. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1605 / 1607

页数：3

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