CATALYTIC HYDROGENOLYSIS OF ESTERS - A COMPARATIVE-STUDY OF THE REACTIONS OF SIMPLE FORMATES AND ACETATES OVER COPPER ON SILICA

被引：37

作者：

AGARWAL, AK ^{[1
]}

CANT, NW ^{[1
]}

WAINWRIGHT, MS ^{[1
]}

TRIMM, DL ^{[1
]}

机构：

[1] UNIV NEW S WALES,SCH CHEM ENGN & IND CHEM,KENSINGTON,NSW 2033,AUSTRALIA

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1987年 / 43卷 / 01期

关键词：

CATALYSIS - CATALYSTS - Copper - CHEMICAL REACTIONS - Reaction Kinetics - ORGANIC COMPOUNDS - Processing - SILICA;

D O I：

10.1016/0304-5102(87)87023-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This study focuses on the reaction of methyl and ethyl formate compared to that of methyl and ethyl acetate in order to quantify these differences. Formates are found to react some 1000 times faster than acetates. The detailed kinetics of formate and acetate hydrogenolysis have been measured and the results correlated with predictions of Langmuir-Hinshelwood models. Experiments with deuterium have been used to explore the mechanisms of the reactions.

引用

页码：79 / 92

页数：14

共 13 条

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