TRANSPARENT, ELECTRICALLY CONDUCTIVE COMPOSITES DERIVED FROM POLYPYRROLE AND POLYVINYL-CHLORIDE) BY VAPOR-PHASE POLYMERIZATION - EFFECT OF ENVIRONMENT ON POLYMERIZATION AND REACTION-MECHANISM

被引：34

作者：

UENO, T ^{[1
]}

ARNTZ, HD ^{[1
]}

FLESCH, S ^{[1
]}

BARGON, J ^{[1
]}

机构：

[1] UNIV BONN,INST PHYS CHEM,D-5300 BONN 1,FED REP GER

来源：

JOURNAL OF MACROMOLECULAR SCIENCE-CHEMISTRY | 1988年 / A25卷 / 12期

关键词：

Iron Compounds - Monomers--Polymerization - Plastics Films--Electric Conductivity - Polyvinyl Chloride - Solvents;

D O I：

10.1080/10601328808055088

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Transparent, electrically conductive composite films were obtained by vapor-phase polymerization of pyrrole into a poly(vinyl chloride) (PVC) matrix containing FeCl3. The effects of water and of organic solvents on the polymerization were investigated. It was found that the conductance of the films increases in the presence of both water vapor and of good solvents or swelling agents for PVC. The conductivity of the films rises with reaction time and so does the rate of increase with higher FeCl3 concentration.

引用

页码：1557 / 1573

页数：17

共 31 条

[1] PHYSICAL-PROPERTIES, ELECTROCHEMISTRY AND ENVIRONMENTAL STABILITY OF POLYACETYLENE COPOLYMERS AND COMPOSITES [J].