AN AC IMPEDANCE STUDY OF THE FRACTAL GEOMETRY OF SILVER FILMS ELECTRODEPOSITED WITHIN A POLYMER MATRIX

被引:11
作者
COMPTON, RG [1 ]
WALLER, AM [1 ]
BLOCK, H [1 ]
CHAPPLES, I [1 ]
机构
[1] CRANFIELD INST TECHNOL,CTR MOLEC ELECTR,SCH IND SCI,CRANFIELD MK43 0AL,BEDS,ENGLAND
关键词
D O I
10.1007/BF01012466
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Silver films (∼10-6m) have been electrodeposited within a polymer matrix (∼10-5 m) of polyvinylidene fluoride trifluoroethylene copolymer 60-40 cast on the surface of a stainless steel electrode. It is shown that the fractal geometry of the polymer-metal interface, which is not open to direct observation, can be characterized by means of ac impedance measurements made on the electrode in acetonitrile solution. © 1990 Chapman and Hall Ltd.
引用
收藏
页码:23 / 25
页数:3
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