A CATALYTIC ASYMMETRIC-SYNTHESIS OF CIS-DECALIN DERIVATIVES VIA PI-ALLYLPALLADIUM INTERMEDIATES

被引：18

作者：

TAKEMOTO, T

NISHIKIMI, Y

SODEOKA, M

SHIBASAKI, M

机构：

[1] UNIV TOKYO,FAC PHARMACEUT SCI,BUNKYO KU,TOKYO 113,JAPAN

[2] HOKKAIDO UNIV,FAC PHARMACEUT SCI,SAPPORO,HOKKAIDO 060,JAPAN

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 24期

关键词：

D O I：

10.1016/S0040-4039(00)92681-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The usefully functionalized cis-decalin derivative 6 has been synthesized in up to 83% ee through the pi-allylpalladium intermediate starting with the prochiral allylic acetate 3.

引用

页码：3531 / 3532

页数：2

共 2 条

[1] ASYMMETRIC-SYNTHESIS CATALYZED BY CHIRAL FERROCENYLPHOSPHINE-TRANSITION METAL-COMPLEXES .1. PREPARATION OF CHIRAL FERROCENYLPHOSPHINES
HAYASHI, T
MISE, T
FUKUSHIMA, M
KAGOTANI, M
NAGASHIMA, N
HAMADA, Y
MATSUMOTO, A
KAWAKAMI, S
KONISHI, M
YAMAMOTO, K
KUMADA, M
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1980, 53 (04) : 1138 - 1151
[2] CATALYTIC ASYMMETRIC C-C BOND FORMATION - ASYMMETRIC-SYNTHESIS OF CIS-DECALIN DERIVATIVES BY PALLADIUM-CATALYZED CYCLIZATION OF PROCHIRAL ALKENYL IODIDES
SATO, Y
SODEOKA, M
SHIBASAKI, M
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1989, 54 (20) : 4738 - 4739

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