FLUORESCENCE SPECTROSCOPY OF ORGANIC-REACTION INTERMEDIATES IN SOLUTION USING A COMMERCIAL SPECTROFLUORIMETER

被引：4

作者：

CASAL, HL

SCAIANO, JC

CHARETTE, GM

SUGAMORI, SE

机构：

[1] Natl Research Council of Canada, Div, of Chemistry, Ottawa, Ont, Can, Natl Research Council of Canada, Div of Chemistry, Ottawa, Ont, Can

来源：

REVIEW OF SCIENTIFIC INSTRUMENTS | 1985年 / 56卷 / 01期

关键词：

CHEMICAL REACTIONS - Reaction Kinetics - FLUORESCENCE - Measurements - LASERS; CHEMICAL - SPECTRUM ANALYSIS;

D O I：

10.1063/1.1138465

中图分类号：

TH7 [仪器、仪表];

学科分类号：

0804 ; 080401 ; 081102 ;

摘要：

The fluorescence spectra of excited free radicals have been recorded using a pulsed laser to generate these reaction intermediates in the modified cell comprtment of a commercial gated spectrofluorimeter. The technique, illustrated with data for the diphenylmethyl and diphenylhydroxymethyl radicals can also be applied to the study of the kinetics of free radical reactions.

引用

页码：23 / 25

页数：3

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