GALVANI POTENTIAL SCALES FOR WATER-NITROBENZENE AND WATER-1,2-DICHLOROETHANE INTERFACES

被引：187

作者：

WANDLOWSKI, T ^{[1
]}

MARECEK, V ^{[1
]}

SAMEC, Z ^{[1
]}

机构：

[1] CZECHOSLOVAK ACAD SCI,J HEYROVSKY INST PHYS CHEM & ELECTROCHEM,CS-18223 PRAGUE 8,CZECHOSLOVAKIA

来源：

ELECTROCHIMICA ACTA | 1990年 / 35卷 / 07期

关键词：

interface between two immiscible electrolyte solutions; single-ion transfer Gibbs energy; voltammetry;

D O I：

10.1016/0013-4686(90)80035-M

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

A practical definition of the absolute Galvani potential scale for a liquid-liquid interface can be based on a set of single-ion transfer Gibbs energies. The consistency of transfer energies for picrate, perchlorate, tetramethylammonium, tetraethylammonium, tetrabutylammonium and tetraphenylarsonium has been examined by using cyclic voltammetry at the interface betwen two immiscible electrolyte solutions. The standard Gibbs energies of transfer of these ions from water to nitrobenzene or 1,2-dichloroethane have been revised. © 1990.

引用

页码：1173 / 1175

页数：3

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