ENERGY-BALANCE OF D2O ELECTROLYSIS WITH A PALLADIUM CATHODE .1. THEORETICAL RELATIONS

被引：10

作者：

BALEJ, J ^{[1
]}

DIVISEK, J ^{[1
]}

机构：

[1] FORSCHUNGSZENTRUM JULICH, NUCL RES CTR, INST APPL PHYS CHEM, W-5170 JULICH 1, GERMANY

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1990年 / 278卷 / 1-2期

关键词：

D O I：

10.1016/0022-0728(90)85125-O

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

On the basis of reliable thermochemical data, the relations for the calculation of the thermoneutral voltage, Etn, of the D2O electrolysis from an approx. 0.1 M LiOD+D2O solution with a Pd cathode with PdDn formation have been derived for stationary and non-stationary courses of electrolysis, as a function of reaction temperature, total pressure and current efficiencies of 02(g) and D2(g) evolution. Due to the lack of thermochemical data for PdDn formation with n > 0.8, the accuracy of the calculated thermoneutral voltage with PdDn formation under non-stationary conditions is lower than for the case of stationary electrolysis. © 1990.

引用

页码：85 / 98

页数：14

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