POROSITY OF SILICA-GELS BY THERMAL-DESORPTION OF LIQUIDS

被引:21
作者
GOWOREK, J
STEFANIAK, W
机构
[1] Faculty of Chemistry, Maria Curie-Sklodowska University
来源
COLLOIDS AND SURFACES | 1992年 / 69卷 / 01期
关键词
PORE STRUCTURE; SILICA GELS; THERMAL DESORPTION;
D O I
10.1016/0166-6622(92)80234-S
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Thermal desorption of liquids was measured using a derivatograph. Alcohols and aliphatic hydrocarbons were used as liquid adsorbates. Pore size distribution curves of silica gels were determined on the basis of thermogravimetric curves using the Kelvin equation. Calculated distributions and total pore volumes were compared with those obtained from the nitrogen method and mercury porosimetry. The influence of heating programs on the shape of the distribution curves is discussed.
引用
收藏
页码:23 / 29
页数:7
相关论文
共 5 条
[1]   THE DETERMINATION OF PORE VOLUME AND AREA DISTRIBUTIONS IN POROUS SUBSTANCES .1. COMPUTATIONS FROM NITROGEN ISOTHERMS [J].
BARRETT, EP ;
JOYNER, LG ;
HALENDA, PP .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1951, 73 (01) :373-380
[2]   STUDIES ON PORE STRUCTURE OF ADSORBENTS AND CATALYSTS .3. COMPARISON OF PORE-SIZE DISTRIBUTIONS DETERMINED IN CHRYSOTILE AND ZIRCONIA SAMPLES BY MERCURY POROSIMETRY AND NITROGEN CAPILLARY CONDENSATION [J].
DEWIT, LA ;
SCHOLTEN, JJ .
JOURNAL OF CATALYSIS, 1975, 36 (01) :36-47
[3]   APPLICATION OF THERMOGRAVIMETRIC ANALYSIS TO THE ESTIMATION OF THE POROSITY OF SILICA-GELS [J].
GOWOREK, J ;
STEFANIAK, W .
COLLOIDS AND SURFACES, 1991, 60 :341-349
[4]  
GOWOREK J, UNPUB MATER CHEM PHY
[5]  
GREGG SJ, 1982, ADSORPTION SURFACE