QUININE MODEL STUDY - STEREOSPECIFIC ALDOL CONDENSATION REDUCTION

被引:2
作者
SOUTH, BE
KASHYAP, RP
MINTER, DA
KRAWIEC, M
WATSON, WH
机构
关键词
D O I
10.1107/S0108270192011016
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The racemate rel-(1R,2R,alphaS)-3-acetoxy-2-(alpha-acetoxy-4-quinolinemethyl)-1-azabicyclo[2.2.2]octane is obtained as the exclusive product in the condensation/reduction reaction sequence. The 1-azabicyclo[2.2.2.]octane moiety is twisted away from the ideal eclipsed geometry.
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页码:607 / 609
页数:3
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