RING PUCKERING AND CH STRETCHING SPECTRA .2. HIGH VIBRATIONAL-STATES OF GASEOUS MONOHYDROGENATED CYCLOPENTENE-3-H(1)

被引：18

作者：

RODINBERCION, S ^{[1
]}

CAVAGNAT, D ^{[1
]}

LESPADE, L ^{[1
]}

MARAVAL, P ^{[1
]}

机构：

[1] UNIV BORDEAUX 1, SPECT MOLEC & CRISTALLINE LAB, CNRS, URA 124, F-33405 TALENCE, FRANCE

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1995年 / 99卷 / 10期

关键词：

D O I：

10.1021/j100010a008

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The excited vibrational states of gaseous cyclopentene 3-HC5D7 have been measured up to Delta v = 7. The second overtone presents essentially two main absorptions corresponding to two distinct conformers. The higher overtones are much perturbed by Fermi resonances with low-energy modes. The contribution of two types of couplings to the ring-puckering motion and to isoenergetic states involving low-energy modes are analyzed and modeled. Through the reconstruction of the spectra, the predominant pathways of the intramolecular vibrational redistribution of the energy (IVR) are discussed,

引用

页码：3005 / 3013

页数：9

共 54 条

[1]

[Anonymous], 1955, MOL VIBRATIONS

[2] C-H LOCAL MODES IN CYCLOBUTENE .1. FTIR STUDIES 700-9000 CM-1 [J].

BAGGOTT, JE ;

CLASE, HJ ;

MILLS, IM .

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1986, 42 (2-3) :319-334

[3] STRUCTURE AND DYNAMICS OF THE EXCITED CH-CHROMOPHORE IN (CF3)3CH [J].

BAGGOTT, JE ;

CHUANG, MC ;

ZARE, RN ;

DUBAL, HR ;

QUACK, M .

JOURNAL OF CHEMICAL PHYSICS, 1985, 82 (03) :1186-1194

[4] C-H AND C-D INTERBOND COUPLING IN CHDCL2 [J].

BAGGOTT, JE ;

LAW, DW ;

MILLS, IM .

MOLECULAR PHYSICS, 1987, 61 (05) :1309-1318

[5] C-H AND C-D INTERBOND COUPLING IN CHD2CL [J].

BAGGOTT, JE ;

NEWNHAM, DA ;

DUNCAN, JL ;

MCKEAN, DC ;

BROWN, A .

MOLECULAR PHYSICS, 1990, 70 (04) :715-727

[6] ROTATION-VIBRATION SPECTRA OF DIATOMIC AND SIMPLE POLYATOMIC MOLECULES WITH LONG ABSORBING PATHS .1. THE SPECTRUM OF FLUOROFORM (CHF3) FROM 2.4-MU TO 0.7-MU [J].

BERNSTEIN, HJ ;

HERZBERG, G .

JOURNAL OF CHEMICAL PHYSICS, 1948, 16 (01) :30-39

[7] VIBRATIONAL ANALYSIS OF C-H STRETCHING OVERTONES IN PYRIDINE AND 2,6-LUTIDINE [J].

BINI, R ;

FOGGI, P ;

DELLAVALLE, RG .

JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (08) :3027-3031

[8] TORSION VIBRATION INTERACTIONS IN HYDROGEN-PEROXIDE .1. CALCULATION OF THE TRANS-BARRIER FOR OH OVERTONE EXCITATIONS UP TO V = 8 [J].

CARPENTER, JE ;

WEINHOLD, F .

JOURNAL OF PHYSICAL CHEMISTRY, 1988, 92 (15) :4295-4306

[9] INFRARED AND RAMAN-STUDY OF MONOHYDROGENATED CYCLOPENTENES-3-H1 AND CYCLOPENTENES-4-H1 - CH STRETCHING VIBRATION AND ITS 2 1ST OVERTONES IN GAS-PHASE [J].

CAVAGNAT, D ;

BANISAEIDVAHEDIE, S .

JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (22) :8529-8538

[10] FAR-INFRARED AND RAMAN-STUDY OF MONOHYDROGENATED CYCLOPENTENE-3-H AND CYCLOPENTENE-4-H RING PUCKERING AND RING TWISTING IN THE GAS-PHASE [J].

CAVAGNAT, D ;

BANISAEIDVAHEDIE, S ;

GRIGNONDUBOIS, M .

JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (13) :5073-5079

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