ONE-POT MULTIFUNCTIONALIZATION OF POLYMETHYL HYDROCARBON PI-LIGANDS - MAXIMUM SPACE OCCUPANCY BY DOUBLE BRANCHING AND FORMATION OF ARBOROLES

被引：62

作者：

MOULINES, F ^{[1
]}

GLOAGUEN, B ^{[1
]}

ASTRUC, D ^{[1
]}

机构：

[1] UNIV BORDEAUX 1,CHIM ORGAN & ORGANOMET,351 COURS LIBERAT,F-33405 TALENCE,FRANCE

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1992年 / 31卷 / 04期

关键词：

D O I：

10.1002/anie.199204581

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Eight, ten, and twelve functional groups can be introduced by the double-branching of the methyl groups in polymethyl hydrocarbon-pi ligands. The one-pot reaction of [CpFe(eta-6-1,2,4,5-Me4C6H2)] with allylbromide provides iron complex 1 (75% yield) which can be converted to the analogous octol or cleaved photochemically to liberate the octaallyl ligand. FE = CpFe+.

引用

页码：458 / 460

页数：3

共 33 条

[1] AMATO I, 1990, SCI NEWS, V138, P288
[2] ORGANOIRON ELECTRON-RESERVOIR COMPLEXES
ASTRUC, D
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1986, 19 (12) : 377 - 383
[3] DESIGN, STABILIZATION, AND EFFICIENCY OF ORGANOMETALLIC ELECTRON RESERVOIRS - 19-ELECTRON SANDWICHES ETA-5-C5R5FE1-ETA-6-C6R'6, A KEY CLASS ACTIVE IN REDOX CATALYSIS
ASTRUC, D
HAMON, JR
ALTHOFF, G
ROMAN, E
BATAIL, P
MICHAUD, P
MARIOT, JP
VARRET, F
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (18) : 5445 - 5447
[4] ORGANO IRON COMPLEXES OF AROMATIC-COMPOUNDS - APPLICATIONS IN SYNTHESIS
ASTRUC, D
[J]. TETRAHEDRON, 1983, 39 (24) : 4027 - 4095
[5] BROWN HC, 1975, ORGANIC SYNTHESES VI, P52
[6] BULHEIM E, 1978, SYNTHESIS-STUTTGART, P155
[7] THE USE OF FERROCENE IN ORGANOMETALLIC SYNTHESIS - A 2-STEP PREPARATION OF CYCLOPENTADIENYLIRON ACETONITRILE AND PHOSPHINE CATIONS VIA PHOTOLYSIS OF CYCLOPENTADIENYLIRON TRICARBONYL OR ARENE CATIONS
CATHELINE, D
ASTRUC, D
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1984, 272 (03) : 417 - 426
[8] CHEN YX, 1990, YOUJI HUAXUE, V10, P289
[9] de Gennes P. G., 1983, J PHYS LETT, V44, P351, DOI DOI 10.1051/IPHYSLET:01983004409035100
[10] FILLAUT JL, UNPUB

← 1 2 3 4 →