SYNTHESIS AND CHARACTERIZATION OF MONOOXO ALKYL COMPLEXES OF RUTHENIUM(VI) AND OSMIUM(VI)

被引：25

作者：

MARSHMAN, RW ^{[1
]}

BIGHAM, WS ^{[1
]}

WILSON, SR ^{[1
]}

SHAPLEY, PA ^{[1
]}

机构：

[1] UNIV ILLINOIS,DEPT CHEM,URBANA,IL 61801

来源：

ORGANOMETALLICS | 1990年 / 9卷 / 04期

关键词：

D O I：

10.1021/om00118a079

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Monooxo alkyl complexes of osmium(VI) and ruthenium(VI) with the molecular formula M(O)(CH2SiMe3)4 have been synthesized from ((trimethylsilyl)methyl)magnesium compounds and [PPh4]2[Os(O)2Cl4], [PPN]2[Ru-(O)2Cl4], or [PPh4]2[Os(O)2(OSiMe3)4]. The complexes were characterized by IR, NMR, and UV‒visible spectroscopy and electrochemistry. The molecular structure of Os(O)(CH2SiMe3)4 was determined by single-crystal X-ray diffraction. © 1990, American Chemical Society. All rights reserved.

引用

页码：1341 / 1343

页数：3

共 13 条

[1] TRIPHENYLPHOSPHONIUM AND TRIMETHYL-PHOSPHONIUM HEXACHLOROOSMATES(IV) AND THEIR REACTIONS WITH ALKYLATING-AGENTS - METHYL AND TRIMETHYLSILYLMETHYL OSMIUM COMPOUNDS - TRANS-DI-CHLOROTETRAKIS(TRIMETHYLPHOSPHINE)-OSMIUM(II) - TETRAKIS(TRIMETHYL-SILYLMETHYL)OXOOSMIUM(VI) [J].