MEASUREMENTS OF THE ELECTRIC-FIELD GRADIENT AT CADMIUM IN THE HIGH-TC SUPERCONDUCTOR YBA2CU3O6+X

被引:4
作者
PLANK, H [1 ]
BAUER, O [1 ]
FORKEL, D [1 ]
MEYER, F [1 ]
ROAS, B [1 ]
SAEMANNISCHENKO, G [1 ]
STROBEL, J [1 ]
WOLF, H [1 ]
WITTHUHN, W [1 ]
机构
[1] SIEMENS AG,FORSCHUNGSLAB,W-8520 ERLANGEN,GERMANY
来源
HYPERFINE INTERACTIONS | 1990年 / 61卷 / 1-4期
关键词
D O I
10.1007/BF02407590
中图分类号
O64 [物理化学(理论化学)、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号
070203 ; 070304 ; 081704 ; 1406 ;
摘要
The electric field gradient (EFG) at111Cd probe atoms in YBa2Cu3O6+x has been studied by the perturbed angular correlation (PAC) spectroscopy. After annealing at temperatures below 1000 K the probe atoms are located at the Cu(1) site; above 1100 K they preferentially occupy the Y site, whereas in the intermediate temperature range they also reside on the Ba site. A reduction of the oxygen content from x=1.0 to 0.2 resulted in a decrease of the asymmetry parameter measured at the Ba site, but in an increase of it at the Y site, indicating there a local distortion of the YBa2Cu3O6+x lattice by the Cd impurity. Two different surroundings for the Cd atoms at the Cu(1) site were observed. © 1990 J.C. Baltzer A.G., Scientific Publishing Company.
引用
收藏
页码:1139 / 1142
页数:4
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