TITANIUM AMIDE MOLECULAR PRECURSORS FOR TITANIUM NITRIDE

被引：7

作者：

DRAKE, SR ^{[1
]}

SANDERSON, KD ^{[1
]}

HURSTHOUSE, MB ^{[1
]}

MALIK, KMA ^{[1
]}

机构：

[1] UNIV WALES COLL CARDIFF,SCH CHEM & APPL CHEM,CARDIFF CF1 3TB,WALES

来源：

POLYHEDRON | 1994年 / 13卷 / 02期

关键词：

D O I：

10.1016/S0277-5387(00)86588-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of titanium tetrachloride in toluene at - 78 degrees C with S equivalents of N,N',N''-trimethylethylenediamine yields a monomeric titanium tetrachloride adduct, [TiCl4(Me(2)NCH(2)CH(2)NMeH)] (1). The complex [TiCl2(Me(2)NCH(2)CH(2)NMeH)(2)] (2) is prepared by the reaction of titanium tetrachloride with 4 equivalents of N,N',N''-trimethylethylenediamine at - 78 degrees C. The X-ray crystal structure of 1 reveals that it has a distorted octahedral structure, with the chelating amine ligand in a delta-gauche conformation.

引用

页码：181 / 186

页数：6

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