SYNTHESIS AND STRUCTURE OF A TRICYCLIC BIS(ZIRCONACYCLOPENTADIENE) COMPOUND

被引：21

作者：

DU, B

FARONA, MF

MCCONNVILLE, DB

YOUNGS, WJ

机构：

[1] UNIV N CAROLINA,GREENSBORO,NC 27412

[2] UNIV AKRON,DEPT CHEM,AKRON,OH 44325

来源：

TETRAHEDRON | 1995年 / 51卷 / 15期

关键词：

D O I：

10.1016/0040-4020(94)01125-J

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

1,5-Bis(trimethylsilyl)penta-1,4-diyne was synthesized from trimethylsilylacetylide and 1-trimethylsilyl-3-bromo-1-propyne, and used in a reaction with ''Cp(2)Zr'', giving as the major product 4,6,10,12-tetrakis (trimethylsilyl)-5,-5,11,11-tetrakis (eta(5)-cyclopentadienyl)-5,11-dizirconatricyclo[7,3,0,0(3,)] dodeca-1(12), 3,6,9-tetraene, which was characterized by H-1 and C-13 NMR spectroscopy and x-ray diffraction studies.

引用

页码：4359 / 4370

页数：12

共 9 条

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