SYNTHETICALLY USEFUL MONO-FUNCTIONALIZATIONS OF DIHALOARENES VIA RIEKE METALS

被引：14

作者：

SELL, MS ^{[1
]}

HANSON, MV ^{[1
]}

RIEKE, RD ^{[1
]}

机构：

[1] UNIV NEBRASKA,DEPT CHEM,LINCOLN,NE 68588

来源：

SYNTHETIC COMMUNICATIONS | 1994年 / 24卷 / 16期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1080/00397919408019062

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reaction of dihalobenzenes and 2, 5-dibromothiophene with Rieke magnesium, Rieke zinc, and Rieke calcium at low temperature affords a mono-organometallic intermediate which upon subsequent treatment with an electrophile provides a mono-functionalized aromatic product in excellent chemical yield.

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收藏

页码：2379 / 2386

页数：8

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