KINETICS AND MECHANISM OF SILANE DECOMPOSITION - SILANES AND DISILANES CONTAINING SI-H BONDS

被引：17

作者：

BELL, TN

PERKINS, KA

PERKINS, PG

机构：

[1] UNIV STRATHCLYDE,DEPT PURE & APPL CHEM,GLASGOW G1 1XL,SCOTLAND

[2] SIMON FRASER UNIV,DEPT CHEM,BURNABY V5A 1S6,BC,CANADA

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1984年 / 88卷 / 01期

关键词：

D O I：

10.1021/j150645a029

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

引用

页码：116 / 118

页数：3

共 14 条

[1]

ARMSTRONG DR, 1973, J CHEM SOC DA, V838, P2273

[2] THE ROLE OF THE TRIPLET-STATE IN INSERTION REACTIONS OF SILYLENES [J].

BELL, TN ;

PERKINS, KA ;

PERKINS, PG .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1980, (22) :1046-1047

[3] HEATS OF FORMATION AND DISSOCIATION OF METHYLSILANES AND CHLOROSILANES AND DERIVED RADICALS [J].

BELL, TN ;

PERKINS, KA ;

PERKINS, PG .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1981, 77 :1779-1794

[4] CALCULATION OF ENERGIES OF ACTIVATION FOR SOME GAS-PHASE REACTIONS [J].

BELL, TN ;

PERKINS, PG .

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[5]

BELL TN, J PHYS CHEM

[6] PYROLYSIS OF DISILANE AND RATE CONSTANTS OF SILENE INSERTION REACTIONS [J].

BOWREY, M ;

PURNELL, JH .

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1971, 321 (1546) :341-&

[7] ARRHENIUS PARAMETERS FOR SILENE INSERTION INTO SILICON-HYDROGEN BONDS [J].

COX, B ;

PURNELL, H .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1975, 71 (04) :859-866

[8] FORMATION OF SILYLENES IN THERMOLYSIS OF PENTAMETHYLDISILANE AND 1,1,2-TRIMETHYLDISILANE [J].

DAVIDSON, IMT ;

MATTHEWS, JI .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1976, 72 :1403-1409

[9]

DAVIDSON IMT, 1975, REACTION KINETICS, V1, P212

[10]

Gaspar P.P., 1978, Reactive Intermediates, V1, P229

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