REGIOCONTROL IN THE INTRAMOLECULAR SILYL MODIFIED SAKURAI (ISMS) REACTION - AN EFFICIENT SYNTHESIS OF A DACUS-OLEAE FRUIT-FLY PHEROMONE

被引：44

作者：

MARKO, IE

MEKHALFIA, A

机构：

[1] Department of Chemistry, The University, Sheffield

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 13期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1016/S0040-4039(00)91736-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The ISMS reaction, which initially afforded a mixture of regioisomeric olefins, can now be controlled to produce only the exocyclic alkene. The ISMS methodology was used in a highly efficient synthesis of a Dacus oleae pheromone 8.

引用

页码：1799 / 1802

页数：4

共 15 条

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