2,5-DIHYDROBOROLES AND 1,3-DIHYDRO-1,3-DIBORETES FROM 1,3-DIENES AND ALKYNES FROM REACTIONS WITH DICHLORO(DIISOPROPYLAMINO)BORANE AND ALKALINE-METALS

被引：14

作者：

BROMM, D ^{[1
]}

STALKE, D ^{[1
]}

HEINE, A ^{[1
]}

MELLER, A ^{[1
]}

SHELDRICK, GM ^{[1
]}

机构：

[1] UNIV GOTTINGEN,INST ANORGAN CHEM,TAMMANNSTR 4,W-3400 GOTTINGEN,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 386卷 / 01期

关键词：

D O I：

10.1016/0022-328X(90)80251-T

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of subvalent species generated by the reaction of dichloro(diisopropylamino)borane with sodium/potassium alloy with unsaturated aliphatic hydrocarbons, have yielded the following compounds: the 2,5-dihydroboroles I and II from 1,3-dienes; the 1,3-dihydrodiboretes III and IV from alkynes and the 1-bis(diisopropylamino)boryl-2-trimethylsilylethyne V from bis(trimethylsilyl)ethyne. The compounds have been characterized by elemental analyses and by mass and NMR (1H, 11B, 13C and in part 15N and 29Si) spectroscopy. An X-ray diffraction study has been performed on II. © 1990.

引用

页码：1 / 7

页数：7

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