AN EXAMINATION OF THE INTERACTION OF SILANES CONTAINING CARBON CARBON DOUBLE-BONDS WITH ALUMINUM-OXIDE BY INELASTIC ELECTRON-TUNNELING SPECTROSCOPY

被引：5

作者：

COMYN, J

OXLEY, DP

PRITCHARD, RG

WERRETT, CR

KINLOCH, AJ

机构：

[1] Drs D.P. Oxley and R.G. Pritchard are with the School of Applied Physical Sciences, Leicester Polytechnic, Leicester, LE1 9BH

[2] Dr C.R. Werrett is now with ICI Chemicals and Polymers Limited, Billingham

[3] Dr A.J. Kinloch is with the Department of Mechanical Engineering, Imperial College, London

来源：

INTERNATIONAL JOURNAL OF ADHESION AND ADHESIVES | 1990年 / 10卷 / 01期

关键词：

aluminium oxide; inelastic tunnelling spectroscopy; silanes; solution doping;

D O I：

10.1016/0143-7496(90)90022-P

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Inelastic electron tunnelling spectra were obtained for some silanes with CC bonds doped from solution in acidic aqueous alcohol and from their vapours. Spectra show a high level of hydrolysis of the silanes doped from solution, but only partial hydrolysis from vapour doping. Vinyltrichlorosilane is fully hydrolysed with both methods of doping. A silane containing a methacrylate group is partially saponified. © 1990.

引用

页码：13 / 18

页数：6

共 32 条

[1]

Lee, J Colloid Interface Sci, 27, (1968)

[2]

Bascom, Macromolecules, 5, (1972)

[3]

Sung, Sung, Proc 35th Ann Tech Conf Reinforced Plastics/Composites Inst, (1980)

[4]

Sung, Lee, Sung, Polym Sci Technol, 12 B, (1980)

[5]

Ishida, Koenig, J Polymer Sci Physics Ed, 17, (1979)

[6]

Chiang, Koenig, Spectroscopic characterization of the matrix–silane coupling agent interface in fiber-reinforced composites, Journal of Polymer Science: Polymer Physics Edition, 20, (1982)

[7]

Walker, J Coatings Technol, 52, (1980)

[8]

Walker, J Oil Colour Chem Assoc, 65, (1982)

[9]

Walker, J Oil Colour Chem Assoc, 65, (1982)

[10]

Alexander, Gent, Henriksen, J Chem Phys, 83, (1985)

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