SOLUTIONS OF GALLIUM TRICHLORIDE IN ETHERS - A GA-71 NMR-STUDY AND THE X-RAY STRUCTURE OF GACL3.MONOGLYME

被引：22

作者：

BOCK, S ^{[1
]}

NOTH, H ^{[1
]}

WIETELMANN, A ^{[1
]}

机构：

[1] UNIV MUNICH,INST INORGAN CHEM,MEISERSTR 1,W-8000 MUNICH 2,GERMANY

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1990年 / 45卷 / 07期

关键词：

!sup]71[!/sup]Ga NMR Spectra; cis-Dichloro-bis(dimethylglycolether)gallium-tetrachlorogallate; Gallium Trichloride-Ether; Gallium Trichloride-Tetrahydrofuran;

D O I：

10.1515/znb-1990-0711

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Solutions of GaCl3 in various ethers have been studied by 71Ga NMR spectroscopy. δ7lGa data indicate that the predominant species in diethylether and tetrahydrofuran solutions are GaCl3 · O(C2H5)2-, and GaCl3-2OC2H8, respectively. However, in monoglyme solution dissociation occurs and the product crystallizing from the solution is [cis-GaCL2(monoglyme)2]-GaCl4 as demonstrated by an X-ray structure determination of the solvate GaCl3 · monoglyme. © 1990, Walter de Gruyter. All rights reserved.

引用

页码：979 / 984

页数：6

共 23 条

[1] NUCLEAR MAGNETIC RESONANCE STUDIES WITH GALLIUM-71
AKITT, JW
GREENWOOD, NN
STORR, A
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1965, (AUG): : 4410 - +
[2] Atwood J. L., 1984, J INCLUSION PHENOM, V2, P367, DOI DOI 10.1007/BF00663277
[3] BEANISH JC, 1978, INORG CHEM, V18, P220
[4] FIVE-CO-ORDINATE ADDUCTS OF ALUMINIUM GALLIUM INDIUM SILICON AND GERMANIUM
BEATTIE, IR
GILSON, T
OZIN, GA
[J]. JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1968, (05): : 1092 - &
[5] QUANTITATIVE STUDY OF THE ALUMINUM TRICHLORIDE ACETONITRILE SYSTEM USING X-RAY CRYSTALLOGRAPHY, ELECTRICAL-CONDUCTIVITY, AL-27 AND CHLORINE-35 NUCLEAR MAGNETIC-RESONANCE AND RAMAN-SPECTROSCOPY - CHARACTERIZATION OF THE PENTAKIS(ACETONITRILE)CHLOROALUMINIUM(III) ION IN THE SOLID-STATE AND IN SOLUTIOND
BEATTIE, IR
JONES, PJ
HOWARD, JAK
SMART, LE
GILMORE, CJ
AKITT, JW
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1979, (03): : 528 - 535
[6] BOARDMAN A, 1984, INORG CHIM A-ART LET, V87, pL27, DOI 10.1016/S0020-1693(00)81818-6
[7] CRYSTAL AND MOLECULAR-STRUCTURE OF THE 1-2 ALUMINUM TRICHLORIDE-TETRAHYDROFURAN COMPLEX ALCL3.2THF
COWLEY, AH
CUSHNER, MC
DAVIS, RE
RILEY, PE
[J]. INORGANIC CHEMISTRY, 1981, 20 (04) : 1179 - 1181
[8] STUDY BY X-RAY-DIFFRACTION AND VIBRATION SPECTROMETRY OF COORDINATION-COMPOUNDS OF ALUMINUM HALIDES WITH ACETONITRILE - VIBRATIONAL ANALYSIS OF ALCL(CH3CN)52+ AND ALBR(CH3CN)52+ CATIONS
DALIBART, M
DEROUAULT, J
FOREL, MT
CAILLET, P
[J]. JOURNAL OF MOLECULAR STRUCTURE, 1980, 63 (02) : 233 - 242
[9] VIBRATION SPECTROMETRIC STUDY ON STRUCTURE OF COORDINATION-COMPOUNDS OF ACETONITRILE WITH ALUMINUM HALIDES ALCL3 AND ALBR3
DALIBART, M
FOUASSIER, M
FOREL, MT
[J]. JOURNAL OF MOLECULAR STRUCTURE, 1977, 36 (01) : 7 - 23
[10] SPECTROSCOPIC INVESTIGATION OF ALUMINUM TRIHALIDE-TETRAHYDROFURAN COMPLEXES .2. SOLUTIONS OF ALUMINUM-CHLORIDE OR BROMIDE IN TETRAHYDROFURAN AND IN TETRAHYDROFURAN-DICHLOROMETHANE
DEROUAULT, J
GRANGER, P
FOREL, MT
[J]. INORGANIC CHEMISTRY, 1977, 16 (12) : 3214 - 3218

← 1 2 3 →