MILD CONDITIONS FOR CYCLIZATION OF BETA-TRIKETIDES TO THE CORRESPONDING GAMMA-PYRONES CARRYING ADJACENT CHIRAL CENTERS TOWARD BIOMIMETIC SYNTHESIS OF FULLY SUBSTITUTED GAMMA-PYRONE-CONTAINING NATURAL-PRODUCTS

被引：43

作者：

ARIMOTO, H ^{[1
]}

NISHIYAMA, S ^{[1
]}

YAMAMURA, S ^{[1
]}

机构：

[1] KEIO UNIV,FAC SCI & TECHNOL,DEPT CHEM,YOKOHAMA,KANAGAWA 223,JAPAN

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 39期

关键词：

D O I：

10.1016/S0040-4039(00)97913-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Related to synthetic study on γ-pyrone-containing natural products, conversions of β-triketides having unstable substituents to the corresponding γ-pyrones have successfully been accomplished by the new methods under conditions using (CH3)2S+Cl or Ph3P+CX3 (or Ph3P+X, X Cl, Br) as the oxygen acceptors. © 1990.

引用

页码：5619 / 5620

页数：2

共 3 条

[1] PHOTOSYNTHETIC ELECTRON-TRANSPORT INHIBITION BY PYRONES AND PYRIDONES - STRUCTURE-ACTIVITY-RELATIONSHIPS
ASAMI, T
YOSHIDA, S
TAKAHASHI, N
[J]. AGRICULTURAL AND BIOLOGICAL CHEMISTRY, 1986, 50 (02): : 469 - 474
[2] ILIKONAPYRONE ESTERS, LIKELY DEFENSE ALLOMONES OF THE MOLLUSK ONCHIDIUM-VERRUCULATUM
IRELAND, CM
BISKUPIAK, JE
HITE, GJ
RAPPOSCH, M
SCHEUER, PJ
RUBLE, JR
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1984, 49 (03) : 559 - 561
[3] CONVENIENT SYNTHESIS OF SUBSTITUTED GAMMA-PYRONES
KOREEDA, M
AKAGI, H
[J]. TETRAHEDRON LETTERS, 1980, 21 (13) : 1197 - 1200

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