MIXED CHALCOGEN CARBONYL-COMPOUNDS .2. SYNTHESIS AND CHARACTERIZATION OF FE2RU(MU-3-SE)-(MU-3-TE)(CO)9 AND (ETA-5-C5H5)COFE2(MU-3-SE)(MU-3-TE)(CO)6

被引：21

作者：

CHAKRABARTY, D ^{[1
]}

HOSSAIN, MM ^{[1
]}

KUMAR, RK ^{[1
]}

MATHUR, P ^{[1
]}

机构：

[1] INDIAN INST TECHNOL, DEPT CHEM, BOMBAY 400076, INDIA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 410卷 / 02期

关键词：

D O I：

10.1016/0022-328X(91)80003-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new mixed metal complexes, each containing bridging selenium and tellurium ligands in the same molecule, Fe2Ru(CO)9(mu-3-Se)(mu-3-Te) and (eta-5-C5H5)CoFe2(CO)6(mu-3-Se)(mu-3-Te) have been prepared from the room temperature reactions of Fe2(CO)6(mu-SeTe) with Ru(CO)4(C2H4) and (C5H5)Co(CO)2, respectively. Reaction of (eta-5-C5H5)CoFe2(CO)6(mu-3-Se)(mu-3-Te) with Pt(PPh3)4 forms the previously known (CO)6Fe2(mu-3-Se)(mu-3-Te)Pt(PPh3)2 and on treatment with NaOMe, followed by acidification, Fe2(CO)6(mu-SeTe) is formed.

引用

页码：143 / 148

页数：6

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