DETERMINATION OF BOND-DISSOCIATION ENERGIES VIA ENERGY-RESOLVED COLLISION-INDUCED DISSOCIATION IN A FOURIER-TRANSFORM ION-CYCLOTRON RESONANCE SPECTROMETER

被引:84
作者
HOP, CECA [1 ]
MCMAHON, TB [1 ]
WILLETT, GD [1 ]
机构
[1] UNIV WATERLOO,GUELPH WATERLOO CTR GRAD WORK CHEM,WATERLOO N2L 3G1,ONTARIO,CANADA
来源
INTERNATIONAL JOURNAL OF MASS SPECTROMETRY AND ION PROCESSES | 1990年 / 101卷 / 2-3期
基金
加拿大自然科学与工程研究理事会;
关键词
D O I
10.1016/0168-1176(90)87011-5
中图分类号
O64 [物理化学(理论化学)、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号
070203 ; 070304 ; 081704 ; 1406 ;
摘要
A Fourier transform ion cyclotron resonance (ICR) spectrometer has been used to determine bond dissociation energies via translation energy controlled collisions between mass-selected ions and a stationary target gas. The ions examined were the proton-bound dimers of diethyl ether, acetone and water, which were generated in a high pressure external ion source. A comparison between bond dissociation energies obtained with this technique and literature values showed that the r.f. excitation of ions in the ICR cell produced ions with a well-defined translational energy. Moreover, the translational energy distribution of the ions was narrow, as indicated by the fact that experimentally obtained threshold curves for dissocation were close to computed curves corrected for Doppler broadening.
引用
收藏
页码:191 / 208
页数:18
相关论文
共 45 条
[1]   HIGH MAGNETIC-FIELD FOURIER-TRANSFORM ION-CYCLOTRON RESONANCE SPECTROSCOPY [J].
ALLEMANN, M ;
KELLERHALS, H ;
WANCZEK, KP .
INTERNATIONAL JOURNAL OF MASS SPECTROMETRY AND ION PROCESSES, 1983, 46 (JAN) :139-142
[2]  
ALLEMANN M, 1989, COMMUNICATION
[3]   THE KINETIC-ENERGY DEPENDENCE OF ION MOLECULE COLLISIONS STUDIED BY FT-ICR SPECTROMETRY [J].
BENSIMON, M ;
HOURIET, R .
INTERNATIONAL JOURNAL OF MASS SPECTROMETRY AND ION PROCESSES, 1986, 72 (1-2) :93-98
[4]   COLLISION-INDUCED DISSOCIATION OF PROTON-BOUND ALCOHOL DIMERS BY FOURIER-TRANSFORM MASS-SPECTROMETRY [J].
BURNIER, RC ;
CODY, RB ;
FREISER, BS .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (26) :7436-7441
[5]   DOPPLER BROADENING IN BEAM EXPERIMENTS [J].
CHANTRY, PJ .
JOURNAL OF CHEMICAL PHYSICS, 1971, 55 (06) :2746-&
[7]   COLLISION-INDUCED DISSOCIATION WITH FOURIER-TRANSFORM MASS-SPECTROMETRY [J].
CODY, RB ;
BURNIER, RC ;
FREISER, BS .
ANALYTICAL CHEMISTRY, 1982, 54 (01) :96-101
[8]  
Cooks R.G., 1978, COLLISION SPECTROSCO
[9]   KINETIC STUDY OF PROTON HYDRATE H+ (H2O)N EQUILIBRIA IN GAS-PHASE [J].
CUNNINGHAM, AJ ;
PAYZANT, JD ;
KEBARLE, P .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (22) :7627-+
[10]   THE COLLISION-INDUCED DISSOCIATION OF PROTONATED WATER CLUSTERS STUDIED USING A TRIPLE QUADRUPOLE [J].
DAWSON, PH .
INTERNATIONAL JOURNAL OF MASS SPECTROMETRY AND ION PROCESSES, 1982, 43 (2-3) :195-209