THE 1ST BINUCLEAR IRON(III) COMPLEX WITH A TERMINALLY COORDINATED PHOSPHATO LIGAND - A MODEL-COMPOUND FOR THE OXIDIZED FORM OF PURPLE ACID-PHOSPHATASE FROM BEEF SPLEEN

被引：34

作者：

BREMER, B

SCHEPERS, K

FLEISCHHAUER, P

HAASE, W

HENKEL, G

KREBS, B

机构：

[1] UNIV MUNSTER,INST ANORGAN CHEM,W-4400 MUNSTER,GERMANY

[2] TH DARMSTADT,INST PHYS CHEM,W-6100 DARMSTADT,GERMANY

[3] UNIV DUISBURG,FACHGEBIET ANORGAN CHEM FESTKORPERCHEM,W-4100 DUISBURG,GERMANY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 07期

关键词：

D O I：

10.1039/c39910000510

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of N,N,N',N'-tetrakis(2-benzimidazolylmethyl)-2-hydroxy-1,3-diaminopropane dihydrochloride (Htbpo.2HCl) with Fe(ClO4)3.9H2O and diphenylphosphate yields red crystals of [Fe2Cl2{O2P(OPh)2}(tbpo)(MeOH)](ClO4)2.3MeOH; the X-ray structure shows a phosphate ligand terminally coordinated to Fe(2) and a methanol ligand coordinated to Fe(1).

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页码：510 / 512

页数：3

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