TRANSITION-METAL COMPLEXES OF 1,1'-BIS(2-PYRIDYL)FERROCENE - A CATIONIC RHODIUM(I) AND A SILVER(I) COMPLEX - PREPARATION AND STRUCTURE

被引：27

作者：

TANI, K

MIHANA, T

YAMAGATA, T

SAITO, T

机构：

来源：

CHEMISTRY LETTERS | 1991年 / 11期

关键词：

D O I：

10.1246/cl.1991.2047

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first transition metal complexes of 1,1'-bis(2-pyridyl)ferrocene (1), a cationic rhodium(I) complex, [Rh(cod)(1)]ClO4, (cod = cycloocta-1,5-diene) and a silver(I) complex, [Ag(1) ClO4]2, were prepared and characterized. X-Ray crystallographic analysis of the silver complex revealed that the complex is a dinuclear highly distorted five-coordinate Ag(I) complex with bridging perchlorate ligands, one of rare examples of five-coordinate Ag(I) complexes.

引用

页码：2047 / 2050

页数：4

共 6 条

[1] SYNTHESIS AND X-RAY STRUCTURAL CHARACTERIZATION OF A RHODIUM(I) COMPLEX OF A PYRIDYLDIPHOSPHINE (PNP) TRIDENTATE LIGAND [J].