RESOLUTION OF ALLYLIC ALCOHOLS VIA COPPER(I) COMPLEXES WITH A CHIRAL DIAMINE

被引：12

作者：

CUCCIOLITO, ME

RUFFO, F

VITAGLIANO, A

FUNICELLO, M

机构：

[1] UNIV NAPOLI FEDERICO 2,DIPARTIMENTO CHIM,I-80134 NAPLES,ITALY

[2] UNIV BASILICATA,FAC SCI,DIPARTIMENTO CHIM,I-85100 POTENZA,ITALY

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 01期

关键词：

D O I：

10.1016/0040-4039(94)88192-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

By using the Corey diamine 1,2-diphenyl-N,N'-bis[(2,4,6-trimethylphenyl)methyl]-1,2-diaminoethane, Copper(I) olefin complexes are prepared. When the olefin is a racemic allylic alcohol, selective coordination of one enantiomer is observed Cleavage with aqueous HCl or NaCN allows a two-steps resolution affording excellent enantiomeric excess.

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页码：169 / 170

页数：2

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