OPTICAL-ABSORPTION SPECTRA FOR THE SOLVATED ELECTRON OBSERVED IN THE PULSE-RADIOLYSIS OF CIS-ISOMERS AND TRANS-ISOMERS OF 3-METHYLCYCLOHEXANOL AND 4-METHYLCYCLOHEXANOL

被引：3

作者：

FUJISAKI, N ^{[1
]}

COMTE, P ^{[1
]}

INFELTA, PP ^{[1
]}

GAUMANN, T ^{[1
]}

机构：

[1] FED INST TECHNOL,INST PHYS CHEM,CH-1015 LAUSANNE,SWITZERLAND

来源：

HELVETICA CHIMICA ACTA | 1990年 / 73卷 / 03期

关键词：

D O I：

10.1002/hlca.19900730304

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The absorption band maximum of solvated electrons, λmax(e−s), in 3‐ or 4‐methylcyclohexanols is observed at longer wavelengths (818–837 nm), if the OH group is axial, and at shorter wavelengths (721–723 nm), if it is equatorial. It is surmised that the size of cavity for the solvated electron is larger in the former case and smaller in the latter. Copyright © 1990 Verlag GmbH & Co. KGaA, Weinheim

引用

页码：574 / 577

页数：4

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