ANTIMONY(III)-BUTOXO COMPOUNDS

被引：5

作者：

DETAMPEL, B ^{[1
]}

SCHMIDT, A ^{[1
]}

机构：

[1] UNIV STUTTGART,INST ANORGAN CHEM,PFAFFENWALDRING 55,W-7000 STUTTGART 80,GERMANY

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1992年 / 609卷 / 03期

关键词：

ANTIMONY(III)-BUTOXO COMPOUNDS; SYNTHESES; VIBRATIONAL SPECTRA;

D O I：

10.1002/zaac.19926090306

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Tri(tert.-butoxo)stiban 1 reacts with antimony(III) chloride dependent from the molar ratio to yield Sb(O(t)Bu)2Cl 2 and Sb4Cl7O(O(t)Bu)3, 3 resp.. 3 are discrete molecules with a cage structure. 2 is associated by oxygen bridges. The vibrational spectra of 1-3 are assigned.

引用

页码：35 / 38

页数：4

共 15 条

[1]

ARBUSOV BA, 1977, IAN SSSR KH, P901

[2]

ARBUZOV BA, 1981, B AKAD SCI DIV CHEM, P1270

[3]

ARBUZOV BA, 1980, IZAV AKAD NAUK SSS K, P1788

[4] THE CRYSTAL-STRUCTURES OF [HPY]2[SB2OBRNCL6-N] WHERE N = 0, 2, AND 4 AND HPY = PYRIDINIUM - STABILIZATION BY VERY STRONG N-H...O HYDROGEN-BONDS [J].

BEGLEY, MJ ;

HALL, M ;

NUNN, M ;

SOWERBY, DB .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1986, (08) :1735-1739

[5] STRUCTURE AND MASS-SPECTRA OF THE SERIES SB(OET)3-SBCL3 [J].

BINDER, GE ;

SCHWARZ, W ;

ROZDZINSKI, W ;

SCHMIDT, A .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1980, 471 (12) :121-130

[6] VIBRATIONAL-SPECTRA OF ALKOXOSTIBANES [J].

BINDER, GE ;

ENSINGER, U ;

DORSCH, W ;

SCHMIDT, A .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1983, 507 (12) :163-170

[7] DIALKYLAMINOSTILBANES - PREPARATION AND SPECTRA [J].

ENSINGER, U ;

SCHMIDT, A .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1984, 514 (07) :137-148

[8] METHOXOSTIBANES - STRUCTURE AND VIBRATIONAL-SPECTRA [J].

ENSINGER, U ;

SCHWARZ, W ;

SCHRUTZ, B ;

SOMMER, K ;

SCHMIDT, A .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1987, 544 (01) :181-191

[9] MASS-SPECTRA OF DIALKYLAMINOSTIBANES [J].

ENSINGER, U ;

SCHMIDT, A .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1985, 520 (01) :160-166

[10] MASS-SPECTRA OF ALKOXISTIBANES [J].

ENSINGER, U ;

SCHMIDT, A .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1983, 502 (07) :233-239

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