DECOMPOSITION OF FREON-12 AND METHYL-CHLORIDE OVER SUPPORTED GOLD CATALYSTS

被引：66

作者：

AIDA, T

HIGUCHI, R

NIIYAMA, H

机构：

[1] TOKYO INST TECHNOL, INT COOPERAT CTR SCI & TECHNOL, TOKYO 152, JAPAN

[2] TOKYO INST TECHNOL, DEPT CHEM ENGN, MEGURO KU, TOKYO 152, JAPAN

来源：

CHEMISTRY LETTERS | 1990年 / 12期

关键词：

D O I：

10.1246/cl.1990.2247

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Decomposition of Freon-12 (CCl2F2) and methyl chloride (CH3Cl) over gold catalysts were studied. Au/Co3O4 showed a high activity for CH3Cl but a lesser activity for CCl2F2 while Au/Al2O3 showed moderate activities for the both reactants. The first step of the reactions over Au/Al2O3 was considered as substitution of Cl by surface OH group on support surface.

引用

页码：2247 / 2250

页数：4

共 4 条

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[J]. CHEMISTRY LETTERS, 1989, (11) : 1901 - 1904

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