THEORY OF ANISOTROPIC SUPEREXCHANGE IN INSULATING CUPRATES

Spin-orbit corrections to superexchange are calculated using the method of Moriya [T. Moriya, Phys. Rev. 120, 91 (1960)] for two of the insulating parent compounds of the cuprate superconductors: (1) La2-xNdxCuO4 where the CuO6 octahedra forming each CuO layer are tilted in staggered fashion about an axis which depends on x and temperature and (2) YBa2Cu3O6+x (x less than or similar 0.4) where the CuO layers form CuO2-Y-CuO2 bilayers in which the in-plane O2- ions are displaced uniformly toward the Y3+ layer. For (1) a simple formula is derived for the weak ferromagnetic moment in each CuO layer as a function of the tilting axis and magnitude. For (2) it is shown that the anisotropic corrections to superexchange are different from what has previously been assumed. For the correct spin Hamiltonian a classical Neel state in which the Cu spins are lying in the plane is unstable in a single CuO layer, but when a bilayer is considered there is a critical value of the interlayer exchange coupling which stabilizes this state. For both cases (1) and (2) spin-wave spectra are calculated and shown to compare favorably with experiment.