VANADIUM-CATALYZED NOVEL OXIDATION OF ARYLACETIC ESTERS FOR THE SYNTHESIS OF ARYLGLYOXYLIC ESTERS

被引：13

作者：

CHOUDARY, BM

REDDY, GVS

RAO, KK

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 03期

关键词：

D O I：

10.1039/c39930000323

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Direct synthesis of arylglyoxylic esters in excellent yields from inexpensive arylacetic esters is realised for the first time by the oxidation of activated methylene using vanadium pillared clay as the catalyst and tert-butylhydroperoxide as an oxidant.

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页码：323 / 324

页数：2

相关论文

共 15 条

[1] A NEW VANADIUM-PILLARED MONTMORILLONITE CATALYST FOR THE REGIOSELECTIVE EPOXIDATION OF ALLYLIC ALCOHOLS [J].

CHOUDARY, BM ;

VALLI, VLK ;

PRASAD, AD .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (09) :721-722

[2] VANADIUM-PILLARED MONTMORILLONITE CATALYST FOR SELECTIVE OXIDATION OF SULFIDES TO SULFOXIDES [J].

CHOUDARY, BM ;

RANI, SS .

JOURNAL OF MOLECULAR CATALYSIS, 1992, 75 (01) :L7-L12

[3]

CHOUDARY BM, 1991, P WORKSHOP ADV CATAL, P112

[4] STUDIES ON ASYMMETRIC SYNTHESIS OF ALPHA-AMINO ACIDS .1. A NEW APPROACH [J].

COREY, EJ ;

MCCAULLY, RJ ;

SACHDEV, HS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1970, 92 (08) :2476-+

[5] ELECTRON-PARAMAGNETIC RESONANCE STUDIES ON CONFORMATIONAL STATES AND METAL-ION EXCHANGE PROPERTIES OF VANADIUM BROMOPEROXIDASE [J].

DEBOER, E ;

BOON, K ;

WEVER, R .

BIOCHEMISTRY, 1988, 27 (05) :1629-1635

[6] BROMIDE-ASSISTED HYDROGEN-PEROXIDE DISPROPORTIONATION CATALYZED BY VANADIUM BROMOPEROXIDASE - ABSENCE OF DIRECT CATALASE ACTIVITY AND IMPLICATIONS FOR THE CATALYTIC MECHANISM [J].

EVERETT, RR ;

BUTLER, A .

INORGANIC CHEMISTRY, 1989, 28 (03) :393-395

[7] ISOLATION OF A NEW VANADIUM-CONTAINING NITROGENASE FROM AZOTOBACTER-VINELANDII [J].

HALES, BJ ;

CASE, EE ;

MORNINGSTAR, JE ;

DZEDA, MF ;

MAUTERER, LA .

BIOCHEMISTRY, 1986, 25 (23) :7253-7255

[8]

HELMUT F, Patent No. 2824407

[9] VO(OET)CL2-INDUCED OXIDATIVE DEAMINATION [J].

HIRAO, T ;

OHSHIRO, Y .

TETRAHEDRON LETTERS, 1990, 31 (27) :3917-3918

[10]

LEHNINGER AL, 1975, BIOCHEMISTRY-US, pCH21