PHOTOGENERATED BASE AS CATALYST FOR IMIDIZATION REACTIONS - A NEW DESIGN OF PHOTOSENSITIVE POLYMERS

被引：28

作者：

FRECHET, JMJ ^{[1
]}

CAMERON, JF ^{[1
]}

CHUNG, CM ^{[1
]}

HAQUE, SA ^{[1
]}

WILLSON, CG ^{[1
]}

机构：

[1] IBM CORP,ALMADEN RES CTR,SAN JOSE,CA 95120

来源：

POLYMER BULLETIN | 1993年 / 30卷 / 04期

关键词：

D O I：

10.1007/BF00338468

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The photogeneration of free amines or diamines from soluble organic precursors such as photoactive 2-nitrobenzyl carbamates is useful for the imidization of polymers containing amic acid or amic ester moieties. The base-catalyzed reaction occurs at lower temperatures than the non-catalyzed thermal process and is applicable to the patterning of polymer coatings or thin films.

引用

页码：369 / 375

页数：7

共 28 条

[1] PHOTOGENERATION OF POLYMERIC AMINES - SYNTHESIS, PHOTO-CROSS-LINKING AND PHOTOIMAGING OF COPOLYMERS CONTAINING PHOTOACTIVE CARBAMATE PENDANT GROUPS [J].