POLYMERIC MERCURY COMPLEXES WITH ONE-DIMENSIONAL CHAIN STRUCTURES .2. SYNTHESIS AND CRYSTAL-STRUCTURE OF [(HG(CH2P(O)PH2)2)2BRLI]N

被引：10

作者：

FACKLER, JP ^{[1
]}

KRESINSKI, RA ^{[1
]}

机构：

[1] TEXAS A&M UNIV SYST,MOLEC STRUCT & BONDING LAB,COLLEGE STN,TX 77843

来源：

ORGANOMETALLICS | 1991年 / 10卷 / 09期

关键词：

D O I：

10.1021/om00055a066

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An organomercury complex formulated as [{Hg(CH2P(O)Ph2)2}2Br-Li(THF)4+1 (I) was obtained by the reaction of LiCH2P(O)Ph2 With HgBr2 in THF. Slow evaporation of a solution of I afforded [{Hg(CH2P(O)Ph2)2}2BrLi]n (II), which has a one-dimensional chain structure In the solid state.

引用

页码：3392 / 3395

页数：4

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