LOW-TEMPERATURE METHANE CHLORINATION WITH AQUEOUS PLATINUM CHLORIDES IN THE PRESENCE OF CHLORINE

被引：49

作者：

HORVATH, IT

COOK, RA

MILLAR, JM

KISS, G

机构：

[1] Corporate Research Laboratories, Exxon Research and Engineering Company, Annandale

[2] University of Miami, Coral Gables, FL

来源：

ORGANOMETALLICS | 1993年 / 12卷 / 01期

关键词：

D O I：

10.1021/om00025a004

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of methane with chlorine in water at 125-degrees-C in the presence of platinum chlorides results in the platinum-assisted formation of methyl chloride which is partially hydrolyzed in situ to methanol. Aqueous Na2-[PtCl4] reacts with chlorine at room temperature, resulting in Na2[PtCl6], which is the major species in solution even at 125-degrees-C.

引用

页码：8 / 10

页数：3

共 19 条

[1] BOSWELL MC, 1930, Patent No. 301542
[2] DAVIS JA, 1990, SELECTIVE HYDROCARBO
[3] STEPWISE DISSOCIATION OF TETRACHLOROPLATINATE(II) ION IN AQUEOUS SOLUTION .6. RATES OF FORMATION AND EQUILIBRIA OF CHLORO AQUA COMPLEXES OF PLATINUM(II)
ELDING, LI
[J]. ACTA CHEMICA SCANDINAVICA, 1970, 24 (05): : 1527 - &
[4] STEPWISE DISSOCIATION OF TETRACHLOROPLATINATE(II) ION IN AQUEOUS SOLUTION .5. CHLORIDE ANATIONS OF CHLORO AQUA COMPLEXES OF PLATINUM(II)
ELDING, LI
[J]. ACTA CHEMICA SCANDINAVICA, 1970, 24 (04): : 1341 - &
[5] STEPWISE DISSOCIATION OF TETRACHLOROPLATINATE (II) ION IN AQUEOUS SOLUTION .4. CHLOROTRIAQUAPLATINUM (II) ION
ELDING, LI
[J]. ACTA CHEMICA SCANDINAVICA, 1970, 24 (04): : 1331 - &
[6] THE KINETICS OF HALOGEN ADDITION .26. ALPHA-BETA-ETHYLENIC ACIDS
EVANS, DA
WATSON, TR
ROBERTSON, PW
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1950, (JUN): : 1624 - 1628
[7] GIRODANI M, 1935, ANN CHIM APPL, V25, P163
[8] Gold'shleger N.F., 1969, ZH FIZ KHIM, V43, P2174
[9] NMR UNDER HIGH GAS-PRESSURE
HORVATH, IT
MILLAR, JM
[J]. CHEMICAL REVIEWS, 1991, 91 (07) : 1339 - 1351
[10] HORVATH IT, 1991, REV SCI INSTRUM, V64, P1104

← 1 2 →