[4-PI+2-PI]CYCLOADDITIONS OF O-QUINONES TO FULVENES - A FACILE SYNTHESIS OF BICYCLO[2.2.2]OCTEN-7,8-DIONES

被引：25

作者：

NAIR, V ^{[1
]}

KUMAR, S ^{[1
]}

WILLIARD, PG ^{[1
]}

机构：

[1] BROWN UNIV,DEPT CHEM,PROVIDENCE,RI 02912

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 10期

关键词：

D O I：

10.1016/0040-4039(95)00099-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

3,5-Di-tert-butyl-, 4-tert-butyl-, and 3-methoxy-o-benzoquinones have been shown to undergo thermal cycloaddition to symmetrical and unsymmetrical fulvenes to give bicyclo[2.2.2]octen-7,8-diones in high yields.

引用

页码：1605 / 1608

页数：4

共 14 条

[1]

ALHAMDANI R, 1981, J IRAQI CHEM SOC, V6, P53

[2] DIELS-ALDER REACTION OF NORTHO-BENZOQUINONES WITH ACYCLIC DIENES [J].

ALHAMDANY, R ;

ALI, B .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1978, (09) :397-397

[3] DIELS-ALDER REACTIONS OF ORTHO BENZOQUINONES WITH ACYCLIC DIENES [J].

ANSELL, MF ;

BIGNOLD, AJ ;

GOSDEN, AF ;

LESLIE, VJ ;

MURRAY, RA .

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC, 1971, (08) :1414-&

[4] REACTIONS OF TETRACHLORO ORTHO BENZOQUINONE AND TETRABROMO ORTHO BENZOQUINONE WITH ACYCLIC DIENES [J].

ANSELL, MF ;

LESLIE, VJ .

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC, 1971, (08) :1423-&

[5] REACTIONS OF ORTHO BENZOQUINONES WITH CYCLOPENTADIENE [J].

ANSELL, MF ;

GOSDEN, AF ;

LESLIE, VJ ;

MURRAY, RA .

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC, 1971, (08) :1401-&

[6]

ERICKSON MS, 1992, J ORG CHEM, P1849

[7]

FRIEDRICHSEN W, 1976, LIEBIGS ANN CHEM, P793

[8]

FRIEDRICHSEN W, 1974, TETRAHEDRON LETT, P2469

[9]

FRIEDRICHSEN W, 1976, TETRAHEDRON, P147

[10] CHEMISTRY OF ORTHO-BENZOQUINONES .2. REACTION WITH TETRAPHENYLCYCLOPENTADIENONE [J].

HORSPOOL, WM ;

TEDDER, JM ;

DIN, ZU .

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC, 1969, (13) :1692-&

← 1 2 →