NICKEL-CATALYZED SUBSTITUTION-REACTIONS OF ALLYLIC COMPOUNDS WITH SOFT NUCLEOPHILES - AN EFFICIENT ALTERNATIVE TO PALLADIUM CATALYSIS

被引:49
作者
BRICOUT, H [1 ]
CARPENTIER, JF [1 ]
MORTREUX, A [1 ]
机构
[1] ENSCL,CHIM ORGAN APPL GRP,CATALYSE HETEROGENE & HOMOGENE LAB,CNRS,URA 402,F-59652 VILLENEUVE DASCQ,FRANCE
关键词
D O I
10.1039/c39950001863
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Substitution reactions of allyl alcohol derivatives la-e with diethylamine, phenol and dimethyl malonate are efficiently carried out in the presence of Ni(dppb)(2) (dppb = 1,2-diphenylphosphinobutane) as catalyst and ammonium salts or bases as-promoters or co-reagents.
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页码:1863 / 1864
页数:2
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