2,4,6-TRI(4-PYRIDYL)-1,3,5-TRIAZINE AS A 5-CONNECTING BUILDING-BLOCK FOR INFINITE NETS

被引：107

作者：

BATTEN, SR ^{[1
]}

HOSKINS, BF ^{[1
]}

ROBSON, R ^{[1
]}

机构：

[1] UNIV MELBOURNE,SCH CHEM,PARKVILLE,VIC 3052,AUSTRALIA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 07期

关键词：

COMPLEXES WITH NITROGEN LIGANDS; MERCURY COMPOUNDS; NETWORKS; TRIAZINES;

D O I：

10.1002/anie.199508201

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new three‐dimensional coordination network with cubic symmetry is displayed by the structure of 1 (shown on the right). Compound 1 is obtained from tri(4‐pyridyl)triazine ligands (tpt) and Hg2+ ions, and has a system of interconnected spacious cavities which are occupied by large numbers of solvent molecules and counterions. The coordination sphere of the Hg center is formed by six pyridine substituents, which is very rare for complexes. (Formula Presented.) (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：820 / 822

页数：3

共 14 条

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