OCTAKIS(2,6-DIETHYLPHENYL)OCTASTANNACUBANE

被引：50

作者：

SITA, LR ^{[1
]}

KINOSHITA, I ^{[1
]}

机构：

[1] CARNEGIE MELLON UNIV,DEPT CHEM,PITTSBURGH,PA 15213

来源：

ORGANOMETALLICS | 1990年 / 9卷 / 11期

关键词：

D O I：

10.1021/om00161a008

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Thermolysis of hexakis(2,6-diethylphenyl)cyclotristannane (2) in naphthalene provides red octakis(2,6-diethylphenyl)octastannacubane (1), which has been fully characterized, including crystallographic analysis. Compound 1 represents the first example of the organo stannane cluster series (RSn)n. © 1990, American Chemical Society. All rights reserved.

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页码：2865 / 2867

页数：3

相关论文

共 11 条

[1] OCTA(PHENYLSILASESQUIOXANE)1,3,5,7,9,11,13,15-OCTAPHENYLPENTACYCLO[9.5.1.13,9.15,15.17,13]-OCTASILOXANE ACETONE SOLVATE [J].

HOSSAIN, MA ;

HURSTHOUSE, MB ;

MALIK, KMA .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1979, 35 (SEP) :2258-2260

[2] SUB-VALENT GROUP-4B METAL ALKYLS AND AMIDES .4. ELECTRON-SPIN RESONANCE STUDY OF SOME LONG-LIVED PHOTOCHEMICALLY SYNTHESIZED TRISUBSTITUTED SILYL, GERMYL, AND STANNYL RADICALS [J].

HUDSON, A ;

LAPPERT, MF ;

LEDNOR, PW .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1976, (22) :2369-2375

[3] HEXAKIS(2,4,6-TRIISOPROPYLPHENYL)CYCLOTRISTANNANE (R2SN)3 AND TETRAKIS(2,4,6-TRIISOPROPYLPHENYL)DISTANNENE (R2SN)2 - THEIR UNPRECEDENTED THERMAL INTERCONVERSION AND THE 1ST SOLUTION SPECTRAL CHARACTERIZATION OF A DISTANNENE [J].

MASAMUNE, S ;

SITA, LR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (22) :6390-6391

[4] THE 1ST OCTASILACUBANE SYSTEM - SYNTHESIS OF OCTAKIS-(TERT-BUTYLDIMETHYLSILYL)PENTACYCLO[4.2.0.0/2,5.0/3,8.0/4,7]OCTASILANE [J].

MATSUMOTO, H ;

HIGUCHI, K ;

HOSHINO, Y ;

KOIKE, H ;

NAOI, Y ;

NAGAI, Y .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (16) :1083-1084

[5] MUCH LESS STRAINED CUBANE ANALOGS WITH SI, GE, SN, AND PB SKELETONS [J].

NAGASE, S .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1989, 28 (03) :329-330

[6] IS TETRASILATETRAHEDRANE KINETICALLY STABLE [J].

NAGASE, S ;

NAKANO, M .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1988, 27 (08) :1081-1083

[7]

NAGASE S, 1987, J CHEM SOC CHEM COMM, V60

[8] ISOLATION AND MOLECULAR-STRUCTURE OF THE 1ST BICYCLO[2.2.0]HEXASTANNANE [J].

SITA, LR ;

BICKERSTAFF, RD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (10) :3769-3770

[9] 2,2,4,4,5,5-HEXAKIS(2,6-DIETHYLPHENYL)PENTASTANNA-[1.1.1]PROPELLANE - CHARACTERIZATION AND MOLECULAR-STRUCTURE [J].

SITA, LR ;

BICKERSTAFF, RD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (16) :6454-6456

[10]

SITA LR, IN PRESS J AM CHEM S