ANOMALOUS POLARIZATION - EVIDENCE FOR VIBRONIC COUPLING IN THE ALLYL RADICAL

被引：19

作者：

GETTY, JD

LIU, XM

KELLY, PB

机构：

[1] Department of Chemistry, University of California, Davis

来源：

CHEMICAL PHYSICS LETTERS | 1993年 / 201卷 / 1-4期

关键词：

D O I：

10.1016/0009-2614(93)85062-S

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The resonance Raman spectra of the allyl radical display intensity in the fundamental of non-totally symmetric modes. Measurement of the depolarization ratio on the nu9 and nu12 vibrational modes yields anomalous depolarization values. The anomalous depolarization ratios provide evidence for vibronic coupling of the allyl radical-excited states in terms of B-term scattering.

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页码：236 / 241

页数：6

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