SIMPLE AND EFFICIENT PALLADIUM-CATALYZED CARBONYLATION OF IODOXYARENES IN WATER UNDER MILD CONDITIONS

被引：14

作者：

GRUSHIN, VV ^{[1
]}

ALPER, H ^{[1
]}

机构：

[1] UNIV OTTAWA, DEPT CHEM, 10 MARIE CURIE, OTTAWA K1N 6N5, ONTARIO, CANADA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1993年 / 58卷 / 18期

关键词：

D O I：

10.1021/jo00070a008

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Iodoxyarenes (ArIO2) readily react with CO (1 atm) in water, in the presence of Na2[PdCl4] (0.1%) and Na2CO3 at 40-50-degrees-C, to give the corresponding carboxylic acids, ArCOOH, in 55-89% isolated yield. Particularly attractive features of the reaction are that, unlike most iodoarenes, ArIO2 can be carbonylated in aqueous media without any organic solvents, due to their solubility in water and high reactivity.

引用

页码：4794 / 4795

页数：2

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