AN IMPROVED PROCEDURE FOR REGIOSELECTIVE ACYLATION OF CARBOHYDRATES - NOVEL ENZYMATIC ACYLATION OF ALPHA-D-GLUCOPYRANOSE AND METHYL ALPHA-D-GLUCOPYRANOSIDE

被引：40

作者：

GOTOR, V

PULIDO, R

机构：

[1] Departamento de Química Organometálica, Facultad de Química, Universidad de Oviedo

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1991年 / 02期

关键词：

D O I：

10.1039/p19910000491

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

6-O-Monoesters of alpha-D-glucopyranose and methyl alpha-D-glucopyranoside have been prepared with high yields through a novel enzymatic reaction using oxime esters as acyl transfer agents.

引用

页码：491 / 492

页数：2

共 10 条

[1] ENZYME CATALYZED PREPARATION OF 6-O-ACYLGLUCOPYRANOSIDES
ADELHORST, K
BJORKLING, F
GODTFREDSEN, SE
KIRK, O
[J]. SYNTHESIS-STUTTGART, 1990, (02): : 112 - 115
[2] A HIGHLY SELECTIVE ENZYME-CATALYZED ESTERIFICATION OF SIMPLE GLUCOSIDES
BJORKLING, F
GODTFREDSEN, SE
KIRK, O
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (14) : 934 - 935
[3] GENERAL-ASPECTS AND OPTIMIZATION OF ENANTIOSELECTIVE BIOCATALYSIS IN ORGANIC-SOLVENTS - THE USE OF LIPASES
CHEN, CS
SIH, CJ
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1989, 28 (06): : 695 - 707
[4] REGIOSELECTIVE ACYLATION OF 6-DEOXY-L-HEXOSIDES AND 6-DEOXY-D-HEXOSIDES THROUGH LIPASE-CATALYZED TRANSESTERIFICATION - ENHANCED REACTIVITY OF THE 4-OH FUNCTION IN THE L SERIES
CIUFFREDA, P
COLOMBO, D
RONCHETTI, F
TOMA, L
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1990, 55 (13) : 4187 - 4190
[5] OXIME ESTERS AS NOVEL IRREVERSIBLE ACYL TRANSFER AGENTS FOR LIPASE CATALYSIS IN ORGANIC MEDIA
GHOGARE, A
KUMAR, GS
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (20) : 1533 - 1535
[6] GOGHARE A, 1990, J CHEM SOC CHEM COMM, P134
[7] ENZYMATIC CATALYSIS IN ANHYDROUS ORGANIC-SOLVENTS
KLIBANOV, AM
[J]. TRENDS IN BIOCHEMICAL SCIENCES, 1989, 14 (04) : 141 - 144
[8] KLIBANOV AM, 1990, ACCOUNTS CHEM RES, V23, P144
[9] FACILE ENZYMATIC PREPARATION OF MONOACYLATED SUGARS IN PYRIDINE
THERISOD, M
KLIBANOV, AM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (18) : 5638 - 5640
[10] REGIOSELECTIVE ACYLATION OF SECONDARY HYDROXYL-GROUPS IN SUGARS CATALYZED BY LIPASES IN ORGANIC-SOLVENTS
THERISOD, M
KLIBANOV, AM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (13) : 3977 - 3981

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