CHIRAL BETA-C-LITHIATED BETA-ALKOXY ACRYLATES - EFFICIENT SYNTHONS FOR HIGHLY FUNCTIONALIZED CYCLOPENTENONES

被引：5

作者：

DATTA, A ^{[1
]}

SCHMIDT, RR ^{[1
]}

机构：

[1] UNIV CONSTANCE,FAK CHEM,POSTFACH 5560,W-7750 CONSTANCE,GERMANY

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 26期

关键词：

D O I：

10.1016/S0040-4039(00)60517-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A one step synthesis of highly functionalized cyclopentenones has been developed by the Michael addition of the readily available beta-lithiated acrylate 1A with suitable acceptors.

引用

页码：4161 / 4164

页数：4

共 11 条

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[2] METHYL 3-LITHIO-2-METHYL-3-PHENYLTHIO-2-PROPENOATE AS A ZWITTERIONIC 3-CARBON ADDEND - REACTIONS WITH CARBONYL-COMPOUNDS
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[J]. JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (11) : 3145 - 3152
[6] SCHICK H, 1989, SYNTHESIS-STUTTGART, P477
[7] SCHMIDT RR, 1983, B SOC CHIM BELG, V92, P825
[8] FACILE SYNTHESIS OF FUNCTIONALLY SUBSTITUTED CYCLOPENTENONES AND BUTENOLIDES FROM FUNCTIONAL VINYL CARBANIONS
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[10] SCHMIDT RR, 1985, ORGANIC SYNTHESIS IN, P281

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