KINETICS OF THE N-CHLORINATION OF 2-AMINOBUTYRIC, 3-AMINOBUTYRIC, 3-AMINOISOBUTYRIC AND 4-AMINOBUTYRIC ACIDS IN AQUEOUS-SOLUTION

被引：2

作者：

ANTELO, JM

ARCE, F

PEREZMOURE, JC

机构：

[1] Dpto. Química Física, Universidad de Santiago, Santiago de Compostela

来源：

INTERNATIONAL JOURNAL OF CHEMICAL KINETICS | 1992年 / 24卷 / 12期

关键词：

D O I：

10.1002/kin.550241207

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We studied the kinetics of the N-chlorination of 2-aminobutyric, 3-aminoisobutyric, and 4-aminobutyric acids by sodium hypoclorite in strongly alkaline aqueous solution. As in the case of other amines, the rate of formation of the four N-chloroamino acids was proportional to the concentrations of hypochlorite and amino acid, and inversely proportional to the concentration of hydroxyl ions. A reaction mechanism compatible with these results is proposed and discussed.

引用

页码：1093 / 1101

页数：9

共 10 条

[1]

[Anonymous], [No title captured]

[2] KINETICS AND MECHANISM OF ETHANOLAMINE CHLORINATION [J].