LIQUID-PHASE CATALYTIC-HYDROGENATION USING PALLADIUM ALLOY MEMBRANES

被引：21

作者：

FARRIS, TS ^{[1
]}

ARMOR, JN ^{[1
]}

机构：

[1] AIR PROD & CHEM INC,7201 HAMILTON BLVD,ALLENTOWN,PA 18195

来源：

APPLIED CATALYSIS A-GENERAL | 1993年 / 96卷 / 01期

关键词：

ALKENES; CYLCOHEXENE; HYDROGENATION; MEMBRANES; PALLADIUM ALLOYS;

D O I：

10.1016/0926-860X(93)80004-A

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The hydrogenation of several liquid alkenes was studied over Pd/Ru alloy membranes in either metal or glass membrane reactors. For cyclohexene, cyclo-octadiene, and octadecene as liquids, conversions of ca. 2-5% were common in contrast to the facile conversion of acetylenic alcohols.

引用

页码：25 / 32

页数：8

共 17 条

[1] ANDERSON MA, 1991, Patent No. 5006248
[2] CATALYSIS WITH PERMSELECTIVE INORGANIC MEMBRANES
ARMOR, JN
[J]. APPLIED CATALYSIS, 1989, 49 (01): : 1 - 25
[3] ARMOR JN, 1992, CHEMTECH, P557
[4] Bhave R. R, 1991, INORGANIC MEMBRANES, P64
[5] EGAN BZ, 1989, ORNL DE90004386 ORD
[6] FARRIS TS, 1992, 10TH P INT C CAT BUD
[7] GOTO R, 1970, CHEM ENG, V34, P35
[8] GRYAZNOV VM, 1986, PLATIN MET REV, V30, P68
[9] GRYAZNOV VM, 1981, DISCUSS FARADAY SOC, V72, P73
[10] GRYAZNOV VM, 1983, Patent No. 4388479

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