NONLINEAR-OPTICAL, OPTICAL, AND CRYSTALLOGRAPHIC PROPERTIES OF N-(4-NITRO-2-PYRIDINYL)-PHENYLALANINOL

被引：22

作者：

SUTTER, K ^{[1
]}

KNOPFLE, G ^{[1
]}

SAUPPER, N ^{[1
]}

HULLIGER, J ^{[1
]}

GUNTER, P ^{[1
]}

PETTER, W ^{[1
]}

机构：

[1] SWISS FED INST TECHNOL,INST CRISTALLOG,CH-8092 ZURICH,SWITZERLAND

来源：

JOURNAL OF THE OPTICAL SOCIETY OF AMERICA B-OPTICAL PHYSICS | 1991年 / 8卷 / 07期

关键词：

D O I：

10.1364/JOSAB.8.001483

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

Single crystals of N-(4-nitro-2-pyridinyl)-phenylalaninol [CA index name (S)-beta-((5-nitro-2-pyridinyl)-amino)-benzenepropanol, CA registration number 115416-53-0] were grown from solution. The crystal structure was determined by x-ray analysis: space group P2(1), a = 11.791 angstrom, b = 6.032 angstrom, c = 9.959 angstrom, beta = 100.55-degrees, Z = 2. The refractive indices were determined in the spectral range of 470 to 1320 nm with an interferometric and a conoscopic method that are explained in detail. The highest nonlinear-optical coefficient was d23 = 31 pm/V. The nonlinear-optical properties are discussed in terms of crystalline structure and molecular hyperpolarizabilities.

引用

页码：1483 / 1490

页数：8

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