SYNTHESIS OF NEW TITANIUM OXO CLUSTER COMPOUNDS - X-RAY STRUCTURE OF THE TETRANUCLEAR OXIDE [TI4CL6(MU-2-O2CPH)6(MU-3-O)2]

被引：12

作者：

ALCOCK, NW

BROWN, DA

ROE, SM

WALLBRIDGE, MGH

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 11期

关键词：

D O I：

10.1039/c39920000846

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Titanium-oxo cluster compounds can be obtained in high yields by the action of carboxylic acids on titanium tetrachloride; X-ray structure analysis of the benzoate derivative [Ti4Cl6(mu-2-O2CPh)6(mu-3-O)2] reveals the presence of a previously unknown Ti4O2 core structure.

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页码：846 / 848

页数：3

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