PHOTOLYSIS OF POLYCYCLIC AROMATIC-HYDROCARBONS IN WATER

被引:113
作者
MILL, T [1 ]
MABEY, WR [1 ]
LAN, BY [1 ]
BARAZE, A [1 ]
机构
[1] SRI INT, DEPT PHYS ORGAN CHEM, MENLO PK, CA 94025 USA
关键词
D O I
10.1016/0045-6535(81)90045-X
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The photochemical reactions of 8 mutagenic polycyclic aromatics and heteroatom analogs (PAH) [benz[a]anthracene, benzo[a]pyrene, quinoline, benzo[f]quinoline, 9H-carbazole, 7H-dibenzo[c,g]carbazole, benzo[b]thiophene, dibenzothiophene] were studied. Quantum yields and rate constants in sunlight and at single wavelengths were measured, and half-lives of the PAH as a function of the time of yr were calculated. Product studies and the effect of humic acid and O2 on rates were reported.
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页码:1281 / 1290
页数:10
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