METATHESIS POLYMERIZATION OF NORBORNENE AND ITS DERIVATIVES - RELATIVE STABILITY OF TUNGSTACYCLOBUTANE INTERMEDIATES AND KINETICS OF THEIR RING-OPENING TO FORM TUNGSTEN-CARBENE COMPLEXES

被引：30

作者：

KRESS, J ^{[1
]}

OSBORN, JA ^{[1
]}

AMIREBRAHIMI, V ^{[1
]}

IVIN, KJ ^{[1
]}

ROONEY, JJ ^{[1
]}

机构：

[1] QUEENS UNIV BELFAST,DEPT CHEM,BELFAST BT9 5AG,ANTRIM,NORTH IRELAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1988年 / 17期

关键词：

D O I：

10.1039/c39880001164

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：1164 / 1166

页数：3

共 7 条

[1] MECHANISM OF TITANOCENE METALLACYCLOBUTANE CLEAVAGE AND THE NATURE OF THE REACTIVE INTERMEDIATE [J].

ANSLYN, EV ;

GRUBBS, RH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (16) :4880-4890

[2]

HERRISSON JL, 1971, MAKROMOL CHEM, V141, P161

[3] 1ST DIRECT OBSERVATION OF THE SIMULTANEOUS PRESENCE AND OF THE INTERCONVERSION OF CHAIN-PROPAGATING METAL-CARBENE AND METALLACYCLOBUTANE COMPLEXES IN A CATALYTIC OLEFIN METATHESIS REACTION - THE RING-OPENING POLYMERIZATION OF NORBORNENE [J].

KRESS, J ;

OSBORN, JA ;

GREENE, RME ;

IVIN, KJ ;

ROONEY, JJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (03) :899-901

[4]

KRESS J, 1987, RECENT ADV MECHANIST, P363

[5] KINETICS AND STEREOCHEMISTRY OF THE TITANACYCLOBUTANE TITANAMETHYLENE INTERCONVERSION - INVESTIGATION OF A DEGENERATE OLEFIN METATHESIS REACTION [J].

LEE, JB ;

OTT, KC ;

GRUBBS, RH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (26) :7491-7496

[6] PREPARATION AND REACTIVITY OF SEVERAL ALKYLIDENE COMPLEXES OF THE TYPE W(CHR')(N-2,6-C6H3-I-PR2)(OR)2 AND RELATED TUNGSTACYCLOBUTANE COMPLEXES - CONTROLLING METATHESIS ACTIVITY THROUGH THE CHOICE OF ALKOXIDE LIGAND [J].

SCHROCK, RR ;

DEPUE, RT ;

FELDMAN, J ;

SCHAVERIEN, CJ ;

DEWAN, JC ;

LIU, AH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (05) :1423-1435

[7] TITANACYCLOBUTANES - SUBSTITUTION PATTERN AND STABILITY [J].

STRAUS, DA ;

GRUBBS, RH .

ORGANOMETALLICS, 1982, 1 (12) :1658-1661

← 1 →